<i>p</i> ‐Menthadienes as Biorenewable Feedstocks for a Monoterpene‐Based Biorefinery

نویسندگان

چکیده

Abstract A terpene‐based biorefinery is described that uses crude sulfate turpentine (CST) and gum (GT) to produce mixtures of p ‐menthadienes ( ‐MeDs) as biorenewable terpene feedstocks. An acid catalyzed ring opening reaction (6 m aq. H 2 SO 4 , 90 °C) first used convert the major bicyclic monoterpenes (α‐pinene, β‐pinene, 3‐carene) in untreated CST (or GT with 5 mol% Me S) into monocyclic ‐MeDs. These unpurified sulfurous ‐MeD (α‐terpinene, γ‐terpinene, isoterpinolene) are then feedstocks for oxidative aromatization (OA), ozonolysis, Diels–Alder, hydrogenation reactions ‐cymene, fragrances, anti‐oxidants, drugs, biopolymers, biofuels. Mechanistic studies OA ‐MeDs ‐cymene reveal hydroperoxide acts an initiator polar radical intermediates stabilized by DMSO generated situ through aerobic oxidation S. This enables be converted 50–60% yields (two steps) using a process only requires aqueous acid, oxygen, heat, final distillation step.

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ژورنال

عنوان ژورنال: Advanced sustainable systems

سال: 2021

ISSN: ['2366-7486']

DOI: https://doi.org/10.1002/adsu.202000292